Enabling iron catalyzed Doyle-Kirmse rearrangement reactions with in situ generated diazo compounds

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC02801F, Communication

Katharina J. Hock, Lucas Mertens, Rene Hommelsheim, Robin Spitzner, Rene M Koenigs
Slow addition of sodium nitrite allows the in situ preparation of highly explosive diazo compounds and enables their safe and scalable application in iron catalyzed rearrangement reactions of allylic and...
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