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Δευτέρα 12 Ιουνίου 2017

A Model for C-F Activation by Electrophilic Phosphonium Cations

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC04057A, Communication
Ian Mallov, Tim Johnstone, Darcy Burns, Douglas W Stephan
The synthesis of the electrophilic phosphonium cation (EPC) salt [C10H6(CF3)PF(C6F5)2][B(C6F5)4] 4 was achieved via oxidation of phosphine [C10H6(CF3)P(C6F5)2] 2 with XeF2 to form phosphorane [C10H6(CF3)PF2(C6F5)2] 3 and subsequent fluoride ion...
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