Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC04188H, Communication

Adam D Piascik, Peter J Hill, Andrew D Crawford, Laurence R Doyle, Jennifer Green, Andrew Edward Ashley
The first cationic Fe silyldiazenido complexes, [Fe(PP)2(NN-SiMe3)]+[BArF4]- (PP = dmpe/depe), have been synthesised and thoroughly characterised. Computational studies show the compounds to be useful structural and electronic surrogates for the...
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