Practical In-situ-generation of Phosphinite Ligands for Palladium-catalyzed Carbonylation of (Hetero)aryl Bromides Forming Esters

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC02828H, Communication

Lin Wang, Helfried Neumann, Anke Spannenberg, Matthias Beller
An effective method for alkoxycarbonylation of (hetero)aryl bromides is developed in the presence of in-situ-generated phosphinite ligands tBu2POR (R = nBu, nPr, Et or Me). For this purpose commercially available...
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