Transition-Metal-Free Synthesis of [small beta]-Trifluoromethylated Enamines with Trifluoromethanesulfinate

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC03125D, Communication

Huanfeng Jiang, Wei Huang, Yue Yu, Songjian Yi, Jiawei Li, Wanqing Wu
We have developed a transition-metal free trifluoromethylation protocol between enamines and CF3SO2Na. A wide range of [small beta]-trifluoromethyl substituted enamines were delivered in moderate to high yields with only E-configurations.
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