Ultrafast 25-fs relaxation in highly excited states of methyl azide mediated by strong nonadiabatic coupling [Chemistry]

Highly excited electronic states are challenging to explore experimentally and theoretically—due to the large density of states and the fact that small structural changes lead to large changes in electronic character with associated strong nonadiabatic dynamics. They can play a key role in astrophysical and ionospheric chemistry, as well as...

http://ift.tt/2zyLDbQ