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Πέμπτη 23 Ιουνίου 2016

Organic Photoredox Catalysis for the Oxidation of Silicates: Applications in Radical Synthesis and Dual Catalysis

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04636C, Communication
Louis Fensterbank, Christophe Leveque, Ludwig Chenneberg, Vincent Corce, Cyril Ollivier
Metal free photooxidation of alkyl bis(catecholato)silicates with the organic dye, 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyano-benzene (4CzIPN), allows the smooth formation of alkyl radicals. The latter can be efficiently engaged either with radical acceptors to...
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