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Πέμπτη 4 Αυγούστου 2016

Crystalline anionic complex of scandium nitride endometallo-fullerene: Experimental observation of single-bonded (Sc3N@Ih-C80-)2 dimers

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05550H, Communication
Dmitri V. Konarev, Leokadiya Zorina, Salavat S. Khasanov, Alexey A Popov, Akihiro Otsuka, Hideki Yamochi, Gunzi Saito, Rimma N. Lyubovskaya
Reduction of scandium nitride clusterfullerene, Sc3N@Ih-C80, by sodium fluorenone ketyl in the presence of cryptand[2,2,2] allows the crystallization of the {cryptand[2,2,2](Na+)}2(Sc3N@Ih-C80-)2 2.5C6H4Cl2 (1) salt. The Sc3N@Ih-C80.- radical anions are dimerized...
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