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Δευτέρα 22 Αυγούστου 2016

Electrocatalytic Water Oxidation by a Molecular Cobalt Complex through a High Valent Cobalt Oxo Intermediate

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05773J, Communication
Debasree Das, Santanu Pattanayak, Kundan K Singh, Bikash Garai, Sayam Sen Gupta
Biuret-modified tetraamidomacrocyclic cobalt complex [CoIII-bTAML]- is shown to catalyze electrochemical water oxidation at basic pH leading to formation of O2. Electrochemical and spectroscopic studies indicate a high valent cobalt oxo...
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