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Τετάρτη 11 Απριλίου 2018

Rh(II)/Phosphine-cocatalyzed Synthesis of Dithioketal Derivatives from Diazo Compounds through Simultaneous Construction of Two Different C-S Bonds

Chem. Commun., 2018, Accepted Manuscript
DOI: 10.1039/C8CC01656A, Communication
Changqing Rao, Shaoyu Mai, Qiuling Song
Rhodium(II)/phosphine-cocatalyzed bis-sulfuration of [small alpha]-diazocarbonyl compounds using thiosulfonates as the sulfenylating agent which provided two S moieties was developed via simultaneous inter- and intra-molecular C-S bonds formation. This novel protocol provides...
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