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Τετάρτη 27 Ιουλίου 2016

Hydrogen cleavage by solid-phase frustrated Lewis pairs

GA?id=C6CC04937K

Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC04937K, Communication
Jun-Yi Xing, Jean-Charles Buffet, Nicholas H. Rees, Peter Norby, Dermot O'Hare
We report the direct synthesis of a solid-phase frustrated Lewis pair (s-FLP), reaction with H2 under mild conditions led to heterolytic H-H bond cleavage and the formation of [[triple bond, length as m-dash]SiOB(H)(C6F5)2][tBu3PH].
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