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Πέμπτη 7 Δεκεμβρίου 2017

A chiral scandium-complex-catalyzed asymmetric inverse-electron-demand oxa-Diels-Alder reaction of o-quinone methides with fulvenes

GA?id=C7CC08124C

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C7CC08124C, Communication
Jianlin Zhang, Lili Lin, Changqiang He, Qian Xiong, Xiaohua Liu, Xiaoming Feng
A highly efficient asymmetric [4+2] cycloaddition of o-quinone methides with fulvenes has been realized using a chiral N,N[prime or minute]-dioxide/Sc(III) complex as the catalyst. The corresponding optically active chromane derivatives were obtained in high yields with excellent dr and ee values.
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