The secondary coordination sphere controlled reactivity of a ferric-superoxo heme: Unexpected conversion to a ferric hydroperoxo intermediate by a reaction with a high-spin ferrous heme

Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC02162J, Communication

Perumandla Nagaraju, Takehiro Ohta, Jin-Gang Liu, Takashi Ogura, Yoshinori Naruta
A bio-inspired heme complex involving both a proton donor and an axial imidazole ligand reduces the activation energy for the formation of a ferric hydroperoxo intermediate. A high-spin ferrous heme...
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