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Τρίτη 19 Ιουλίου 2016

Tunable Reactivity of Geminal Bis(silyl) Enol Derivatives Leading to Selective exo-IEDDA or Sakurai Allylation with [small beta],[gamma]-Unsaturated Ketoester

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC04593F, Communication
zhenlei song, Zubao Gan, Zhiwen Chu, Jia Hu, Zhishan Su, Changwei Hu, Lu Gao
Two contrasting pathways in a SnCl4-catalyzed reaction of geminal bis(silyl) enol derivatives with [small beta],[gamma]-unsaturated ketoesters have been achieved by tuning the R group in the enol moiety. While electron-donating Bn-substituted...
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