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Δευτέρα 22 Αυγούστου 2016

A Non-Dissociative Open-Flask Hydroboration with Ammonia Borane: Ready Synthesis of Ammonia-Trialkylboranes and Aminodialkylboranes

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC06151F, Communication
P Veeraraghavan Ramachandran, Michael P. Drolet, Ameya S Kulkarni
Under open-flask conditions, ammonia borane hydroborates olefins in refluxing tetrahydrofuran. Unlike conventional hydroboration, the Lewis base (ammonia) is not dissociated from the boron center. Terminal alkenes selectively provide ammonia-trialkylborane complexes....
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