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Δευτέρα 19 Σεπτεμβρίου 2016

Enantioselective construction of branched 1,3-dienyl substituted quaternary carbon stereocenters by asymmetric allenyl Claisen rearrangement

GA?id=C6CC06481G

Chem. Commun., 2016, Advance Article
DOI: 10.1039/C6CC06481G, Communication
Yangbin Liu, Haipeng Hu, Lili Lin, Xiaoyu Hao, Xiaohua Liu, Xiaoming Feng
The enantioselective Claisen rearrangement of allenyl vinyl ethers was realized to access branched 1,3-dienyl-substituted all-carbon quaternary stereocenters using a NiII-N,N[prime or minute]-dioxide complex.
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