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Δευτέρα 31 Οκτωβρίου 2016

Self-assembly and photocatalytic H2 evolution activity of two unprecedented polytantalotungstates based on the largest {Ta18} and {Ta18Yb2} clusters

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC07649A, Communication
Peng Huang, Chao Qin, Yu Zhou, Yu-Mei Hong, Xinlong Wang, Zhong-Min Su
Two unprecedented polytantalotungstates (POTTs), Cs16K16Na4[Ta18P12W90(OH)6(H2O)2O360][round bullet, filled]24H2O (1), Cs26K2H2[Yb2Ta18P12W90(OH)6(H2O)16O360][round bullet, filled]52H2O (2) based on the largest {Ta18} and {Ta18Yb2} clusters, respectively, were hydrothermally synthesized. Photocatalytic study revealed that 1 and 2 exhibit significant ultraviolet...
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