A Binder-Free and Free-Standing Cobalt Sulfide@Carbon Nanotube Cathode Material for Aluminum-Ion Batteries

Abstract

Rechargeable aluminum-ion batteries (AIBs) are considered as a new generation of large-scale energy-storage devices due to their attractive features of abundant aluminum source, high specific capacity, and high energy density. However, AIBs suffer from a lack of suitable cathode materials with desirable capacity and long-term stability, which severely restricts the practical application of AIBs. Herein, a binder-free and self-standing cobalt sulfide encapsulated in carbon nanotubes is reported as a novel cathode material for AIBs. The resultant new electrode material exhibits not only high discharge capacity (315 mA h g⁻¹ at 100 mA g⁻¹) and enhanced rate performance (154 mA h g⁻¹ at 1 A g⁻¹), but also extraordinary cycling stability (maintains 87 mA h g⁻¹ after 6000 cycles at 1 A g⁻¹). The free-standing feature of the electrode also effectively suppresses the side reactions and material disintegrations in AIBs. The new findings reported here highlight the possibility for designing high-performance cathode materials for scalable and flexible AIBs.

Binder-free and free-standing cobalt sulfide@carbon nanotube is applied as cathode for aluminum-ion batteries for the first time with enhanced electrochemical performance. The optimized electrode exhibits a high capacity (315 mA h g⁻¹ at 100 mA g⁻¹), excellent rate performance, and remarkable cycling stability (297 mA h g⁻¹ at 100 mA g⁻¹ after 200 cycles; 87 mA h g⁻¹ at 1 A g⁻¹ after 6000 cycles).

from #MedicinebyAlexandrosSfakianakis via xlomafota13 on Inoreader http://ift.tt/2BeHhZl
via IFTTT