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Δευτέρα 8 Ιανουαρίου 2018

A nickel-catalyzed anti-carbometallative cyclization of alkyne-azides with organoboronic acids: synthesis of 2,3-diarylquinolines

GA?id=C7CC08408K

Chem. Commun., 2018, Advance Article
DOI: 10.1039/C7CC08408K, Communication
Gadi Ranjith Kumar, Ravi Kumar, Manda Rajesh, Maddi Sridhar Reddy
An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido phenyl propargyl alcohols with aryl boronic acids is achieved using Ni(acac)2 as the catalyst to access 2,3-diaryl quinolines.
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