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Πέμπτη 14 Ιανουαρίου 2016

Addition of Silylated Nucleophiles to [small alpha]-Oxoketenes

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C5CC10217K, Communication
Yohan Dudognon, Marc Presset, Jean Rodriguez, Yoann Coquerel, Xavier Bugaut, Thierry Constantieux
A general evaluation of silylated nucleophiles to intercept transient [small alpha]-oxoketenes generated by microwave-assisted Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds is presented. Original scaffolds and synthetic intermediates are accessed in a rapid,...
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