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Πέμπτη 14 Ιανουαρίου 2016

Direct Difunctionalization of Activated Alkynes via Domino Oxidative Benzylation/1,4-Aryl Migration/Decarboxylation Reactions under Metal-free Conditions

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C5CC10084D, Communication
Tao Miao, Dong Xia, Yang Li, Pinhua Li, Lei Wang
An oxidative difunctionalization of aryl alkynoate via benzyl radical initiated intramolecular 1,4-aryl migration and decarboxylation tandem process was developed in presence of tert-butyl hydroperoxide (TBHP) as an oxidant, which provides...
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