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Δευτέρα 4 Ιανουαρίου 2016

An expedient synthesis of functionalized 1,4-diketone-derived compounds via silyloxyallyl cation intermediates

GA?id=C5CC09763K

Chem. Commun., 2016, Advance Article
DOI: 10.1039/C5CC09763K, Communication
Jacob R. Stepherson, Frank R. Fronczek, Rendy Kartika
Herein we describe the synthesis of highly functionalized 1,4-diketones that are readily differentiated as monosilylenol ethers via direct capture of silyloxyallyl cations by silyl enolates under Bronsted acid catalysis.
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