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Δευτέρα 27 Ιουνίου 2016

Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC05222C, Communication
Qing Pan, Leon Freitag, Tanja Kowacs, Jane Falgenhauer, Jeroen P. Korterik, Derck Schletwein, Wesley Browne, Mary Pryce, Sven Rau, Leticia Gonzalez, Han Vos, Annemarie Huijser
The contrasting early-time photodynamics of two related Ru/Pt catalysts with very different photocatalytic H2 generation capabilities are reported. Ultrafast equilibration (535+/-17 fs) creates an electron reservoir on the peripheral ligands...
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