Directed synthesis, X-ray crystal structures, computational analysis, and characterization of dimethyldiindenocorannulene (15), cyclooctenodiindenocorannulene (16), and N-heptyldiindenocorannulenemaleimide (17) motivate a model for curved aromatics, blending bowl-in-bowl assemblies with nanocarbon material properties.
A robust synthesis of three diindenocorannulene derivatives is reported, X-ray crystal structures; photophysical and electrochemical properties, and computational results are also reported.
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