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Τρίτη 30 Μαΐου 2017

Reversible formation and cleavage of Pt[rightward arrow]Ag dative bonds in a pre-organized cavity of a luminescent heteropolynuclear platinum(II) complex

GA?id=C7CC03447D

Chem. Commun., 2017, Advance Article
DOI: 10.1039/C7CC03447D, Communication
Misa Ueda, Shinnosuke Horiuchi, Eri Sakuda, Yoshihide Nakao, Yasuhiro Arikawa, Keisuke Umakoshi
A heteropolynuclear complex can reversibly capture an Ag(I) ion and release it from the pre-organized cavity by the concerted formation and cleavage of Pt[rightward arrow]Ag dative bonds and Ag-C(ipso) bonds, respectively.
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