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Τετάρτη 28 Ιουνίου 2017

Silver(I)-Induced Higher-Ordered Structure Based on Planar Chiral Tetrasubstituted [2.2]Paracyclophane

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC03615A, Communication
Masayuki Gon, Yasuhiro Morisaki, Yoshiki Chujo
Optically active phenylene-ethynylene dimers with pyridine groups based on a planar chiral 4,7,12,15-tetrasubstituted [2.2]paracyclophane were synthesized. The chiral conformation was controlled by pyridine-Ag(I) coordinations. After Ag(I) coordination, the resulting higher-ordered...
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