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Τρίτη 6 Ιουνίου 2017

Single Site Silica Supported Tetramethyl Niobium by the SOMC Strategy: Synthesis, Characterization and Structure-Activity Relationship in Ethylene Oligomerization Reaction

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC02585H, Communication
Ali Hamieh, Raju Dey, Bijan Nekoueishahraki, manoja samantaray, Yin Chen, edy Abou-Hamad, Jean-Marie Basset
Silica supported Tetramethyl niobium complex [([identical with]SiO)NbMe4] 2 has been isolated by surface alkylation of [([identical with]SiO-)NbCl3Me] 1 with dimethyl zinc in pentane. 1 can be easily synthesized by grafting of NbCl3Me2...
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