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Πέμπτη 7 Ιανουαρίου 2016

Metal-exchangeable macrocycles: from a bismetallo-Ru2/Zn triangle to a Ru2/Fe triangular assembly

GA?id=C5CC08460A

Chem. Commun., 2016, Advance Article
DOI: 10.1039/C5CC08460A, Communication
Die Liu, Xiaoyu Yang, Yiming Li, Pingshan Wang
Ru2/Zn and Ru2/Fe based bismetallo-organic triangles had been prepared from a predesigned metallo-organic ligand possessing two uncomplexed free terpyridines. A quantitative coordination constant controlled metallo-transformation from a Ru2Zn to a Ru2Fe triangle had been established through an in situ site to site procedure at room temperature.
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