Turning on the red phosphorescence of a [Ru(tpy)(bpy)(Cl)]Cl complex by amide substitution: self-aggregation, toxicity, and localization of an emissive ruthenium-based amphiphile

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC02989F, Communication

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Bianka Siewert, Michiel Langerman, Yusaku Hontani, John T.M. Kennis, Vincent H. S. van Rixel, Bart Limburg, Maxime A Siegler, Victorio Saez Talens, Roxanne E. E. Kieltyka, Sylvestre Bonnet
Coupling the notoriously non-emissive complex [Ru(tpy)(bpy)(Cl)]Cl (tpy = 2,2':6',2"-terpyridine, bpy = 2,2'-bipyridine) to a C12 alkyl chain via an amide linker on the 4' position of the terpyridine yielded a...
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