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Τετάρτη 17 Φεβρουαρίου 2016

The synthesis and efficient one-pot catalytic "self-breeding" of asymmetrical NC(sp3)E-hybridised pincer complexes

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Chem. Commun., 2016, Accepted Manuscript
DOI: 10.1039/C6CC00763E, Communication
Xiangyuan Yang, Wee Shan Tay, Yongxin Li, Sumod A Pullarkat, Pak-Hing Leung
Cyclopalladation of the pyridyl-substituted chiral phosphine sulfide (N-P=S) and oxide (N-P=O) ligands afforded the asymmetric N-C(sp3)*-S and N-C(sp3)*-O pincer complexes. When applied as catalysts in asymmetric hydrophosphination, the newly developed...
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