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Τρίτη 6 Ιουνίου 2017

Cobaloxime-catalyzed hydration of terminal alkynes without acidic promoters

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC03919K, Communication
Shengtai Hou, Hongjian Yang, Bin Cheng, Hongbin Zhai, Yun Li
Cobaloxime (Co(dmgBF2)2[middle dot]2H2O), an inexpensive first-row transition-metal complex, catalyzed hydration of terminal alkynes gave the corresponding methyl ketones in good to excellent yields under neutral conditions (additional protic acids and silver...
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